Setting alias domain results in smtp error for multicompanies

Question

Hi ( Avoid unnecessary introductions :P ), in Odoo v8 I setup incomming and outgoing email.
When I leave Alias domain empty I can send emails.  When I put the Alias Domain it does not work.
General Settings >
Manage multiple companies checked
Alias Domain :  mydomain.com
Currently I have only 1 user administrator@mydomain.com and 1 company MyDomain.
The error in the logs :
MailDeliveryException: (u'Mail Delivery Failed', u"Mail delivery failed via SMTP server 'smtp.office365.com'.
SMTPDataError

Victor Bendig · Answer

Update on the issue,
Created a sencond user, added an Alias for the second user under Settings> Technical > Email > Aliases
Aliased Model : Users
Record Thread ID : 1
Default Values :{}
Alias Contact Security : Everyone
Owner :Second User
Parent Model: Users
Parent Record Thread ID: 1

Attempted to send emails with the second user but I got the error:
SMTPDataError:550  5.7.60 SMTP; Client does not have permissions to send as this sender
The first user is still able to send emails without errors

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